The present age is moving through Industry 4.0 with massive technological developments. Supply chains have become digital, keeping sync with consumer demands and preferences. The recent pandemic has reinforced the need of embracing digital technologies in managing supply chains effectively. Therefore, it is necessary that supply chains adopt 5G mobile technologies. In this regard, the present study aims to discern the critical issues for the successful adaptation of 5G technologies for supply chain management (SCM) in developing countries such as India. The success factors for the adaptation of 5G in Indian supply chains are derived from the discussions made in the related past work regarding the challenges of implementing 5G technology. Then, the listed factors are finalised through initial rounds of face-to-face discussions with a focus group of five experts. Then, a q-rung-orthopair-fuzzy (qROFS)-based rating scale is used to rate the success factors. A new qROF-weighted-neutrality-average (q-ROFWNA)-based full-consistency method (FUCOM) approach for multicriteria decision-making (MCDM) problems involving group decision making is utilised to find out the critical success factors. Based on the comparative analysis of 17 success factors (grouped into four main factors), the spectrum availability, awareness of technology and usage, the development of supporting technologies and smart cities, and skill development are found to be the top five critical factors for the successful adaptation and implementation of 5G technologies in SCM. We further carry out a sensitivity analysis and validation test and observe that our model provides a reliable and stable solution.
This paper describes the first record of the critically endangered gravid female Spiny butterfly ray, Gymnura altavela (Linnaeus, 1758), in the northern Mediterranean and simultaneously the only record of the species in this century for the Adriatic Sea. The female (173 cm disc width and 43.25 kg total weight) was captured at approximately 200 m, off Vlorë in the southern Adriatic Sea off Albania on 12th of May 2022. Upon necropsy, seven near-term fetuses (mean 328 ± 6.47 mm disc width and mean 355 ± 20.06 g in total weight) were transported for further in-vitro incubation. These results represent the deepest capture for the species, as well as the largest litter size and largest size at birth in the Mediterranean Sea which indicates the need for further research.
Introduction: Preoperative carbohydrate oral (CHO) drinks attenuate the surgical stress response; however, the effects of CHO supplementation on the neutrophil-to-lymphocyte ratio (NLR) as an inflammatory and immunology-based predictor remain unclear. This study evaluated the effects of preoperative CHO loading on NLR values and complications following open colorectal surgery compared with a conventional fasting protocol. Methods: Sixty eligible participants having planned for routine and open colorectal cancer surgery from May 2020 to January 2022 were prospectively and randomly allocated to either the control (fasting) group, whose members discontinued oral intake beginning the midnight before surgery, or the intervention (CHO) group, whose members consumed a CHO solution the night before surgery and 2 h prior to anaesthesia. NLR was assessed at 06:00 h before surgery (baseline) and at 06:00 h on postoperative days 1, 3, and 5. The incidence and severity of postoperative complications were assessed by Clavien-Dindo Classification up to postoperative day 30. All data were analysed using descriptive statistics. Results: Postoperative NLR and delta NLR values were significantly higher in controls (p < 0.001; p < 0.001). Control group participants also demonstrated grade IV (n = 5; 16.7%, p < 0.01) and grade V (n = 1; 3.3%, p < 0.313) postoperative complications. There were no major postoperative complications in the CHO group. Conclusion: Preoperative CHO consumption reduced postoperative NLR values and the incidence and severity of postoperative complications following open colorectal surgery, compared with a preoperative fasting protocol. Preoperative carbohydrate loading may improve recovery following colorectal cancer surgery.
Two copper(II) complexes of 4-chloro- and 4-dimethylaminobenzaldehyde nicotinic acid hydrazones were prepared and characterized by elemental analysis, mass spectrometry, infrared and electron spectroscopy and conductometry. These rare examples of bis(hydrazonato)copper(II) complexes are neutral complex species with copper(II) center coordinated with two monoanionic bidentate O,N-donor hydrazone ligands coordinated in enol-imine form. The interaction of hydrazone ligands and corresponding copper(II) complexes with CT DNA and BSA was investigated. Copper(II) complexes are slightly effective in binding the DNA than pristine hydrazones. The results indicate groove binding or moderate intercalation which are not significantly affected by the nature of substituent at hydrazone ligands. On contrary, affinities of two copper(II) complexes toward BSA significantly differs and depends on the nature of the substituent, however in absence of thermodynamic data difference in nature of binding forces cannot be excluded. The complex bearing electron-withdrawing 4-chloro substituent has larger affinity toward BSA compared to 4-dimethyamino analogue. These findings were theoretically supported by molecular docking study.
This collective discussion brings together six women scholars of and from the post-Yugoslav space, who, using personal experiences, analyze the dynamics of knowledge production in international relations (IR), especially regarding the post-Yugoslav space. Working in Global North academia but with lived experiences in the region we study, our research is often subjected to a particular gaze, seeped in assumptions about “ulterior” motives and expectations about writing and representation. Can those expected to be objects of knowledge ever become epistemic subjects? We argue that the rendering of the post-Yugoslav space as conflict-prone and as Europe's liminal semi-periphery in the discipline of IR cannot be decoupled from the rendering of the region and those seen as related to it as unable to produce knowledge that, in mainstream discussions, is seen as valuable and “objective.” The post-Yugoslav region and those seen as related to it being simultaneously postcolonial, postsocialist, and postwar, and characterized by marginalization, complicity, and privilege in global racialized hierarchies at the same time, can make visible specific forms of multiple colonialities, potentially creating space for anti- and/or decolonial alternatives. We further make the case for embracing a radical reflexivity that is active, collaborative, and rooted in feminist epistemologies and political commitments.
Basketball is one of the popular sports in the world, and physical performance is becoming increasingly important in basketball as the game evolves. The aim of the study was to investigate the effects of a 3-week modified complex training on athletic performance of women's national basketball players. An experimental study involved the participation of 12 highly trained female basketball players (national team of Bosnia and Herzegovina). Observed variables before and after 3-weeks of modified complex training were 300 yards test, 20-yards test, lane agility and beep test. Means and standard deviations for each of the variables were calculated, and differences pre-to-post performance changes were examined using a paired sample t-test. Three weeks of specific complex training sessions show a statistically significant increase in all tested variables, 300 yards (p≤.001); 20 yards (p≤.001); Lane agility (p≤.001) and beep test (p=.028). It can be concluded that applied complex training program has significantly improved studied parameters of condition preparation of elite female basketball players.
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