Submicron and nanosized powders have gained significant attention in recent decades due to their broad applicability in various fields. This work focuses on ultrasonic spray pyrolysis, an efficient and flexible method that employs an aerosol process to synthesize titanium-based nanoparticles by transforming titanium oxy-sulfate. Various parameters are monitored to better optimize the process and obtain better results. Taking that into account, the influence of temperature on the transformation of titanium oxy-sulfate was monitored between 700 and 1000 °C. In addition to the temperature, the concentration of the starting solution was also changed, and the flow of hydrogen and argon was studied. The obtained titanium-based powders had spherical morphology with different particle sizes, from nanometer to submicron, depending on the influence of reaction parameters. The control of the oxygen content during synthesis is significant in determining the structure of the final powder.

Online learning self-efficacy is associated with significant psychological outcomes among college students. Nevertheless, research on investigating self-efficacy among college students during COVID-16 pandemic is limited. The aim of the present study was to investigate the role of self-efficacy beliefs regarding online learning in predicting subjective well-being of college students. One hundred and sixty-five college students were recruited for the study. Participants completed the Online Learning Self-Efficacy Scale (OLSES), the Subjective Well-Being Scale (SWBS), as well as a socio-demographic information form including items about COVID-19-related anxiety and perceived impact of COVID-19 on daily life. Regression analyses showed that overall self-efficacy predicted the subjective well-being scores. However, only time management subdimension of self-efficacy predicted subjective well-being. Our findings indicate that high levels of self-efficacy beliefs, and, in particular beliefs regarding time management, are associated with elevated levels of subjective well-being among college students. Interventions regarding self-efficacy in online learning environments may aid college students who have lower levels of subjective well-being during COVID-19.

The Pacific large low-shear-velocity province (LLSVP), as revealed by cluster analysis of global tomographic models, hosts multiple internal anomalies, including a notable gap (~20° wide) between the central and eastern Pacific. The cause of the structural gap remains unconstrained. Directly above this structural gap, we identify an anomalously thick mantle transition zone east of the East Pacific Rise, the fastest-spreading ocean ridge in the world, using a dense set of SS precursors. The area of the thickened transition zone exhibits faster-than-average velocities according to recent tomographic images, suggesting perturbed postolivine phase boundaries shifting in response to lowered temperatures. We attribute this observation to episodes of Mesozoic-aged (250 to 120 million years ago) intraoceanic subduction beneath the present-day Nazca Plate. The eastern portion of the Pacific LLSVP was separated by downwelling because of this ancient oceanic slab. Our discovery provides a unique perspective on linking deep Earth structures with surface subduction.

A percolation model with nucleation and object growth is studied by Monte Carlo simulations on a triangular lattice with finite-size impurities. The growing objects are needle-like objects and self-avoiding random walk chains. Results are obtained for three different shapes of impurities covering three lattice sites—needle-like, angled and triangular. In each run through the system, the lattice is initially randomly occupied by impurities of a specified shape at a given concentration ρimp. Then, the seeds for the object growth are randomly distributed at a given concentration ρ. The percolation and jamming properties of the growing objects are compared for the three different impurity shapes. For all the impurity shapes, the percolation thresholds θp∗ have lower values in the growing needle-like objects than in the growing self-avoiding random walk chains. In the presence of needle-like and angled impurities, the percolation threshold increases with the impurity concentration for a fixed seed density. The percolation thresholds have the highest values in the needle-like impurities, and somewhat lower values in the angled impurities. On the other hand, in the presence of the triangular impurities, the percolation threshold decreases with the concentration of impurities.

The Kunming-Montreal Global Biodiversity Framework (GBF) is the most ambitious agreement on biodiversity conservation and sustainable use to date. It calls for a whole-of- society approach aimed at halting and reversing the loss of biodiversity worldwide. To support its implementation, the Monitoring Framework of the GBF lays out how Parties to the Convention on Biological Diversity are expected to report their progress. Given the need for capacity-building and investment to operationalize the Monitoring Framework, Parties established an expert group to provide guidance on its implementation, including a gap analysis to identify the strengths and limitations of the Monitoring Framework. We present the results of the gap analysis, highlight where more work on the Monitoring Framework is needed and provide recommendations on implementing and improving it to allow effective and comprehensive tracking of progress across all elements of the GBF’s Goals and Targets. We find that using required indicators (headline and binary), the Monitoring Framework fully covers 20% of the Goals’ and Targets’ elements and partially covers an additional 42%. Including optional (component and complementary) indicators improves full coverage to 24% and an additional 49% partial coverage. For 13% of elements, no indicators are available. While the Monitoring Framework will enable progress towards meeting the Goals and Targets of the GBF, substantial investment is still required to collect the necessary data to compute indicators, infer change, and effectively monitor progress. We highlight both immediate and long-term solutions and offer guidance on important next steps that will progressively improve the efficacy of the Monitoring Framework.

Patients suffering from cholelithiasis have an increased risk of developing cardiovascular complications, particularly ischemic myocardial disease. Ursodeoxycholic acid (UDCA), already used in clinical practice for the treatment of cholelithiasis and related conditions, has proven antioxidative, anti-inflammatory, and cytoprotective effects. Therefore, the aim of this study was to investigate the cardioprotective effect of UDCA pre-treatment on isoprenaline-induced myocardial injury in rats. Male Wistar albino rats were randomized into four groups. Animals were pre-treated for 10 days with propylene glycol + saline on days 9 and 10 (control), 10 days with propylene glycol + isoprenaline on days 9 and 10 (I group), 10 days with UDCA + saline on days 9 and 10 (UDCA group), and 10 days with UDCA + isoprenaline on days 9 and 10 (UDCA + I group). UDCA pre-treatment significantly reduced values of high-sensitivity troponin I (hsTnI) and aspartate aminotransferase (AST) cardiac markers (p < 0.001 and p < 0.01, respectively). The value of thiobarbituric acid reactive substances (TBARS) was also decreased in the UDCA + I group compared to the I group (p < 0.001). UDCA also significantly increased glutathione (GSH) levels, while showing a tendency to increase levels of superoxide dismutase (SOD) and catalase (CAT). The level of nuclear factor kappa-light-chain-enhancer of activated B cells (NF-κB) expression, a key regulatory gene of inflammation, was diminished when UDCA was administered. A reduction of cardiac damage was also observed in the UDCA pre-treated group. In conclusion, UDCA pre-treatment showed a cardioprotective effect on isoprenaline-induced myocardial injury in rats, primarily by reducing oxidative stress and inflammation.

Background and Objectives: Left ventricular aneurysm (LVA) is associated with a decline in cardiac function, evidenced by a lower ejection fraction (EF), due to the reduction in the proportion of functional myocardium. The left ventricular end-diastolic volume (LVEDV), the left ventricular aneurysm volume (LVAV), and the LVAV/LVEDV ratio show a strong correlation with the EF. The aim of this study was to determine LVA characteristics post-myocardial infarction (basal vs. apical) and to evaluate the impact of aneurysm volume in diastole (LVAVd), aneurysm area in diastole (LVAAd), and their respective ratios with LVEDV and area (LVEDA) on the EF, in order to identify the most critical predictive factors for assessing and managing the negative impact of aneurysms on cardiac function. Materials and Methods: This observational study included post-infarction LVA patients at the “Dedinje” Cardiovascular Institute in Belgrade, Serbia, undergoing routine transthoracic echocardiography. Echocardiography assessed volumes (LVEDV, LVESV, LVAVd, LVAVs) and areas (LVAAd, LVAAs, LVEDA, LVESA) using the area–length method. The ratios (LVAVd/LVEDV, LVAVs/LVESV, LVAAd/LVEDA, LVAAs/LVESA) were derived from these measures. The left ventricular EF was calculated using Simpson’s method. Results: Basal aneurysms showed a significantly smaller LVAVd (p = 0.016), LVAAd (p = 0.003), and LVAAs (p = 0.029) compared to apical aneurysms, indicating that basal aneurysms are smaller in size. However, there was no significant difference in the EF and overall LV volumes between the groups, although the basal aneurysm group had a slightly higher EF and end-diastolic volume, with a slightly lower end-systolic volume. Furthermore, when comparing the correlation between the EF and the LVAVd, the LVEDV, and the LVAVd/LVEDV ratio, the results indicate that the LVAVd had the greatest impact on the EF (−0.695), followed by the LVAVd/LVEDV ratio (−0.637), and the lowest correlation is between the EF and LVEDV. A similar relationship is observed when comparing the EF with the LVESV, the LVAVs, and the LVAVs/LVESV ratio. Conclusions: Basal aneurysms are significantly smaller than apical ones, yet EF and LV volumes remain similar between the groups, with the EF being slightly higher in the basal group. In cases of LVA, LVAVd shows the strongest negative correlation with the EF, indicating its significant impact on systolic function, followed by the LVAVd/LVEDV ratio, with the weakest correlation seen between the EF and LVEDV.

Introduction: Aim of this study is to analyze gender-related epidemiological characteristics of cauda equina syndrome (CES) in Zenica-Doboj Canton in 10 years period. Methods: The study was conducted in the Zenica-Doboj Canton, and data were obtained from the time period between 2012 to 2022. The study included a total sample of 1709 patients diagnosed with disc herniation who underwent surgical decompression. In total, 48 patients developed cauda equine syndrome (CES). Results: The analysis unveiled noteworthy gender disparities, with male predominance (79.2% vs. 20.8%, p<0.001) and varying employment distributions (males: 23.7% unemployed, 63.2% employed, 13.1% retired; females: 40.0% unemployed, 20.0% employed, 40.0% retired, p<0.001). The calculated OR for 2012-2022 was 2.969 (95% CI: 1.576-5.593, p=xxx), signifying a substantial gender-incidence relationship for CES. CES-I incidence ranged 0.80-1.60/100,000 and CES-R ranged 0.25-0.83/100,000. Highest CES incidence was 4.17/100,000 (2015); the lowest was in 2019 with no CES-R cases reported. Male incidence peaked at 2.64/100,000 (2018), and the lowest was 1.06/100,000 (2013, 2017). For females, the highest was 1.17/100,000 (2018, 2021), with no cases reported in certain years. The affected level demonstrated gender differences, with L4/L5 prevalence in males (47.4%) and L3/L4 in females (50%, p=0.165). Conclusion: This study revealed a higher incidence of CES in males compared to females in the Zenica-Doboj Canton. The heterogenicity of data regarding CES occurring due to the lumbar disc herniation is significant. This indicates a clear need for additional research and epidemiological studies that would highlight the population of patients that have higher risk of CES onset.

The World Health Organization (WHO) released guidelines for physical activity (PA), sedentary behavior, and sleep for children under 5 years of age in 2019, but there are no reports on the adherence to the guidelines in southeastern Europe. This study aimed to: (i) determine the proportion of preschool children (aged 3-5 years) who met the WHO guidelines and examine the feasibility of the proposed protocol for the SUNRISE study in Bosnia and Herzegovina (B&H), and (ii) define sex-, and urban/rural-living-specifics in movement-behaviors, anthropometrics, gross-motor-skills, fine-motor- skills, and cognitive-skills. The sample comprised 115 preschool children (63 girls and 52 boys), residing in urban (n = 66) and rural areas (n = 49) from B&H. Participants were tested on movement behaviors (PA, sleep time, screen time) by accelerometry and comprehensive questionnaires. Body height, weight, body mass index, executive function, fine-, and gross-motor skill, and cognitive function were also measured. The results showed that PA-, sleep duration-, and screen time guidelines were met by 64%, 74% and 53% of children, respectively, while only 23% of the children met all three guidelines on movement behaviors. Boys exhibited higher PA than girls, but no differences in gross- and fine motor skills and cognitive functioning were recorded between the sexes. Children living in urban and rural environments did not differ in any of the studied variables. Results evidenced preschool children from B&H being in line with other samples globally about study variables. Although PA was higher in boys than in girls it was not translated to differences in motor skills. Further studies on larger samples and other environments are warranted.

This particular article will utilize a constructivist approach, in order to analyze the various dynamics of the involvement of civil society in environmental governance in Bosnia and Herzegovina, specifically focusing on its position inside the European Union. Based on the philosophical principles of constructivism, this study investigates how civil society, as an active and socially produced participant, influences the complex landscape of environmental regulation in the European Union. The study primarily investigates the constructive mechanisms that promote engagement between civil society and government authorities. It specifically tackles the areas of lobbying, grassroots mobilization, and engagement with partners. Moreover, it analyzes the influence of civil society on environmental policies and their enhancement through the analysis of case studies and theoretical methodologies centered in constructivism. This study intends to clarify the ongoing conflict and constructivism in environmental governance and demonstrate how civil society’s constructive engagement facilitates democratic decision-making and contributes to the advancement of sustainability objectives.

This study explores relationships between societal culture value dimensions and preferred leader behavior in Bosnia and Herzegovina (BIH). It is one of the first studies that provide an overview of the dimension of Monumentalism in BIH and bring together all seven cultural dimensions, thus contributing to their overall understanding. Data in two observed regions (region Bosnia, region Herzegovina) have not yielded significant differences in preferred leader behavior across regions, and regarding cultural dimensions, significant differences among regions were found only for Individualism and Masculinity, implicating relatively homogenous culture in BIH. While Power Distance has no significant correlations with any of the preferred leadership behaviors, significant correlations were found for other cultural dimensions. The study’s results contribute to a deeper understanding among leaders and employees and enhance managerial effectiveness.

This study examines the relationships between societal cultures and preferred leadership behaviors across seven Slavic nations: Bosnia and Herzegovina, Croatia, the Czech Republic, North Macedonia, Poland, Russia (in two regions), and Serbia. The results depict variations in the associations between cultural dimensions and leadership behaviors within the Slavic context, revealing both consistent patterns and intriguing differences across countries, underscoring their cultural diversity. The obtained results contribute to the field of cross-cultural leadership and provide deeper insights into leadership dynamics within Central and Eastern European countries.

Mental health is deteriorating far and fast globally post-COVID. Though there were already over one billion people living with mental disorders pre-pandemic, in the first year of COVID-19 alone, the prevalence of anxiety and depression soared by 25% worldwide. In light of the chronic shortages of mental health resources and talents, along with disruptions of available health services caused by pandemic-related restrictions, technology is widely believed to hold the key to addressing the rising mental health crises. However, hurdles such as fragmented and oftentimes suboptimal patient protection measures substantially undermine technology’s potential to address the global mental health crises reliably and at scale. To shed light on these issues, this paper aims to discuss the post-pandemic mental health challenges and opportunities, and the strategies and solutions the global mental health community could leverage to protect and elevate society’s mental health in the long run.