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Publikacije (14)

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Borislav N. Malinović, Tijana Đuričić, Pero Sailović, Dajana Dragić, Sanda Pilipović, Aleksandra Borković, Draženko Bjelić

This study explores the effectiveness of electrocoagulation (EC) for removing toxic hexavalent chromium (Cr(VI)) from industrial wastewater using iron and aluminum electrodes in both batch and continuous modes. Iron electrodes demonstrated superior performance, achieving up to 99.8% Cr(VI) removal in batch mode at an optimal current density of 5 mA/cm2, while continuous operation at 50 L/h achieved comparable removal after 30 minutes, with slightly lower efficiency due to reduced retention time. The lowest specific energy consumption (2.82 kWh/kg Cr(VI)) was also recorded under these optimal conditions, highlighting economic feasibility. Fourier-transform infrared (FTIR) analysis of the sludge confirmed the reduction of Cr(VI) to the less toxic Cr(III), primarily in the form of Cr(OH)3. Characteristic peaks indicate Cr-O vibrations in chromium hydroxide, while the presence of hydroxyl (-OH) groups confirms the formation of iron hydroxide complexes that facilitate Cr(VI) adsorption and precipitation. Additional spectral features suggest the presence of iron oxides, further supporting the electrocoagulation mechanism involving the generation of coagulant species in situ. Overall, the results affirm EC as a highly efficient and cost-effective treatment method, particularly suitable for large-scale applications.

Tijana Đuričić, Draženko Bjelić, Aleksandra Borković, Dajana Dragić, Sanda Pilipović, Borislav N. Malinović

In addition to the already well-known application in metal production, electroplating, electrochemical energy sources, electrochemistry is also applied in other branches of industry. Today, electrochemical technologies for the treatment of wastewater and drinking water are increasingly present. In recent years, new advanced oxidation processes based on electrochemical technology - Electrochemical advanced oxidation processes (EAOPs), have been developed for the treatment of persistent pollutants, which cannot be removed by conventional water treatments. EAOPs are based on “in situ” electrolytic formation of strong oxidants in an electrochemical reactor, able to degrade almost all organic pollutants. Despite their effectiveness in degrading different types of pollutants, the biggest challenge for EAOPs is high electricity demand to power these systems, which can have serious consequences from both an ecological and an economic point of view. The use of electricity from the distribution network to power electrochemical reactors is the biggest barrier to achieving commercial success of this technology. A possible solution to this challenge is the application of direct solar UV radiation to produce electric energy by use of a solar photovoltaic (PV) arrays for power supply of EAOPs. The aim of the research was to demonstrate the feasibility of using EAOPs directly powered by PV systems, as a sustainable system for efficient water treatment.

Borislav N. Malinović, Neda Brestovac, Dario Marjanovic, Dajana Dragić, Draženko Bjelić, T. Djuričić

The subject of this research wasto verify the feasibility of implementing green chemistry principles within the business company „Omorika Reciklaža“ Ltd. situated in Johovac near Doboj, Bosnia and Herzegovina. The objective of this study wasto conduct a detailed assessment of the company's facilities and operations, using environmental audits, to identify technological processes (production lines), energy and waste flows, capacities, product range, and other pertinent factors crucial for theapplication of green chemistry principles. Special emphasis was placed on analyzing each substance that constitutes a raw material, whether used individually or as part of mixtures.The assessment of safety data sheets involvedutilizing the CAS registration numbers of substances from the Chemical Abstracts Service, cross-referenced with the ECHA database (European Chemicals Agency). The outcomes, attained through an exhaustive analysis of each substance, were presented as a "chemical inspection" of the company. Through the analysis of all substances and mixtures in the technological process (chemical inspection), as well as the capacity of production flows, energy and resource flows, wastewater, and waste, the potential for enhancing the technological process wasidentified. This involvedreducing dust levels in the workspace, decreasing electricity consumption (utilizing renewable sources), and substituting particularly hazardous chemicals used in the technological process. KEYWORDS:green chemistry; chemical safety; SVHC;environmentalaudit

Draženko Bjelić, D. N. Markić, D. Prokić, Borislav N. Malinović, Andrea Andrejevic Panic

Background The main goal of the paper is to review the existing state and propose a model solution for the introduction of the waste-to-energy concept in the Republic of Serbia and Bosnia and Herzegovina, as these Balkan countries are a source of high pollution due to the inefficient use of fossil fuels and the operation of coal-fired power plants. Besides, these countries have very low level of waste management, which results in the uncontrolled disposal of a large amount of waste which consists of plastic and microplastic materials which are difficult to decompose in natural ecosystems. Methods Considering the type and objectives of the study, a mixed research method was chosen as a combination of exploratory research, descriptive research, explanatory research, and modeling. Results The main result of the research shows the unfavorable situation in the field of waste management in the Republic of Serbia, as well as in Bosnia and Herzegovina. Both countries have adopted adequate strategies and plans, but waste management is not implemented accordingly, Nevertheless, numerous problems create considerable opportunities for improvement, especially regarding the potential for energy production from waste, which is an important approach to implementing the circular economy model. The study showed that the situation is particularly unfavorable in rural areas. Hence, the research proposes (a) a novel model for waste-to-energy governance and (b) a novel model for waste-to-energy management in rural areas. The research was done, and models were developed based on the examples of the Republic of Serbia, and Bosnia and Herzegovina. However, the results can be used in countries with a similar level of waste management and with a larger share of rural areas. Conclusions The paper emphasizes the importance of a holistic and systemic approach to waste management, with emphasis on using waste-to-energy concept as particularly applicable in the transition to circular economy. This study proposes a model for the integration of waste management (with emphasis on plastic and microplastic) and energy efficiency, presenting a model of approach that can be used in countries that are at the beginning of introducing a circular economy.

Waste is a by-product of human activities and living. With the increase in the number of inhabitants, the standard of living and urbanization, the quantities of municipal waste are increasing day by day. Every segment of waste management starting from generation, through collection, storage, transport, treatment and disposal can pose a potential hazard to human health and the environment. Waste management in Republic of Srpska is organized at the regional level. Since only waste disposal is still present in the Republic of Srpska, the regional approach implies that there is a landfill on the territory of one of the local self-government units, where all local self-government units in the region dispose of waste. In addition, waste disposal in illegal and unregulated landfills is still evident. LGUs or utility companies often face a lack of money to organize waste collection, with the result that not all households are covered by waste collection. In recent years, a lot has been invested in infrastructure, such as the filling of containers and containers and the purchase of new or newer used waste collection vehicles. Future directions of improving the waste management system in Republic of Srpska must go in the direction of sustainable waste management, ie waste management in a way to reduce the negative impact on human health and the environment, as well as avoiding leaving this problem to future generations.

Marko Balaban, Valentina Balaban Radić, Draženko Bjelić, Aleksandar Bursać, Milenko Jaćimović, Brankica Gegić, Aleksandar Lukač, D. Marić et al.

Waste disposal is just one of the segments in solid municipal waste management system. During the entire life cycle of waste, starting from waste generation, through storage, collection, transport, recycling, treatment and disposal, several different pollutants are emitted. By disposing solid waste, non-road mobile machinery (NRMM) emits various pollutants into the air such as CO2, CO, NMVOC, PM, PAHs, heavy metals, etc. These substances can pose certain problems for human health and the environment. The subject of this study is the calculation of air emissions of CO2, CH4, N2O, NMVOC, PM10, CO, Cd, Cr and PAHs (chrysene and benz[a]anthracene) from NRMM which are included in the activities of receiving and disposing of waste at the Banja Luka landfill. The study evaluates the emission of pollutants using the EEA guidelines for the assessment of the emission of pollutants into the air, based on the consumption of diesel fuel during the year. This study, which is based on the calculation of NRMM emissions at the Banja Luka landfill, should serve as an example not only to other landfills but also to sectors that use NRMM on the importance of keeping track of pollutant emissions. The goal is to look at these emissions and introduce changes and improvements in this sector by replacing old NRMMs with new ones, optimizing operation, using diesel of satisfactory quality, etc.

Abstract Waste transport is just one of the segments in the solid municipal waste management. Throughout the entire waste life cycle, starting by generation of waste, via storing, collecting, transporting, recycling, treating and depositing, several different polluting substances are emitted. The solid waste transport, apropos, transporting vehicles emit into the air different pollution substances such as CO2, CO, NOx, NMVOC, PM, PAHs etc. These substances can present certain problems for human health and environment. The research subject of this study is the analysis of solid waste transportation within the Banja Luka region (B&H), from towns and municipalities belonging to the region and transporting their mixed municipal waste to the Banja Luka landfill. In the analysis, following parameters are included: distance to the landfill, type of vehicle used for the waste transportation, type of the engine, vehicle capacity and the number of tours during a year. The study estimates the emission of CO, NOx, NMVOC, and PM2.5 during one year using the listed parameters and by applying EMEP/EEA guidelines for estimating the emission of polluting substances into the air. The largest emission of polluting substances (CO, NOx, NMVOC and PM2.5) is from the oldest vehicles. The newest vehicles had a significantly lesser emission of these polluting substances into the air. The recommendation for decreasing the emission from the transportation vehicles is to organise the transfer-stations, procure new vehicles, optimise the collection routes and decrease the number of tours, as well as to better the usage of the vehicle capacity level.

Borislav N. Malinović, T. Djuričić, Dajana Dragić, Rade Malesevic, Draženko Bjelić

A. Jukić, E. Vidović, F. Faraguna, Lucija Rebrović, Mihovil Medić, Đ. Ačkar, Veronika Barišić, Ivana Flanjak et al.

The main objectives of waste management are environmental preservation, the safeguarding of human health, and natural resources conservation. Material flow analysis/ substances flow analysis (MFA/SFA) method takes into account the consideration of the “metabolic” system of waste management, which means monitoring waste flows and substances within the model for waste management, and examining all inputs and outputs in the system, as well as their evaluation and comparison. Modeled scenarios in the Banjaluka region of the Republic of Srpska (RS) were developed in accordance with both the European Union (EU) and RS legislation, as well as relevant municipal waste management strategic documents. Modeled municipal solid waste (MSW) management scenarios are compared with the current waste management system. Using MFA/SFA (waste flow, carbon, and nitrogen), a complete view of flow, transformations, and final waste disposal and substances in modeled scenarios of waste management is realized. Results of this study suggest that in the future, more activity should be based on the separate collection and recycling, compared to the current, inadequate MSW management system that is based only on the disposal of waste. The combination of material and substance flows analyses is an effective tool in the decision-making process for the development and improvement of MSW management.

Draženko Bjelić, D. N. Markić, Zeljka Sobot Pesic, M. Sorak, Olivera Kikanovic, Ljiljana Vukic, M. Ilić, A. Mihajlov

In this paper life cycle assessment was applied to analyze and evaluate, from an environmental point of view, current and alternatives to the current solid waste management system in Banjaluka region. The current system, which is disposal on landfill, has significant adverse environmental impacts caused by methane emissions from landfill. Therefore, four different scenarios were developed as alternatives to the current waste management system. Landfilling with energy recovery, separate collection of packaging waste, incineration and anaerobic digestion were considered in these scenarios. The functional unit in this study is 100,000 tons which is the amount of municipal waste which is generated within one year in Banjaluka. The assessment in this study was based on results from modelling performed in the EASETECH model. The improvement of gas collection in the current scenario and its utilisation for the purpose of creating energy will have a positive effect on the environment. Increasing separation collection of packaging waste and reducing biodegradable waste will have a positive effect on the environment. The separation and recycling of packaging waste should begin as soon as possible and policies that promote source separated collection should be implemented.

Draženko Bjelić, H. Stevanović-Čarapina, Dragana Ne kovic Markic, eljka obot Pe ic, A. Mihajlov, Ljiljana Vukic

This paper presents the application of life cycle assessment (LCA) modelling used in the process of comparing the best technology for disposal municipal solid waste (MSW) in the Banjaluka region. Three scenarios were considered: unsanitary landfill, sanitary landfill with gas collection and burning on flare and sanitary landfill with energy recovery. The Banjaluka landfill is currently an unsanitary landfill because a system for collecting and treating gas has not yet been implemented. The environmental impact from the current waste management system is dominated by the landfill, which has no gas collection. The construction of the gas collecting system with flare is planned for 2015 (70% efficiency, during 30 year period) which will make the Banjaluka landfill a sanitary landfill. The long-term plan encompasses using the landfill gas for heat generation (39% efficiency) and electric energy (19% efficiency), as well as improvement of leachate collection system (from present 60% to 80%) and gas collection (from present 70% to 85%). Landfill with energy recovery leads to saved emission and avoided impact potential in several environmental categories. A sensitivity analysis is applied to the sanitary landfill with gas collection and burning on flare. The results of sensitivity analysis for sanitary landfill with flare indicate that the overall environmental impact is sensitive to the gas collection efficiency, bulk density and period of gas collection.

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