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Marko Bošković

Društvene mreže:

M. Bošković, M. Frantlović, E. Milinković, P. Poljak, D. V. Radović, Jelena N. Stevanovic, M. Sarajlić

Self-powered sensors are gaining a lot of attention in recent years due to their possible application in the Internet of Things, medical implants and wireless and wearable devices. Human breath detection has applications in diagnostics, medical therapy and metabolism monitoring. One possible approach for breath monitoring is detecting the humidity in exhaled air. Here, we present an extremely sensitive, self-powered sensor for breath humidity monitoring. As a power source, the sensor uses electromagnetic energy harvested from the environment. Even electromagnetic energy harvested from the human body is enough for the operation of this sensor. The signal obtained using the human body as a source was up to 100 mV with an estimated power of 1 nW. The relatively low amount of energy that could be harvested in this way was producing a signal that was modulated by an interdigitated capacitor made out of electrochemically activated aluminum. The signal obtained in this way was rectified by a set of Schottky diodes and measured by a voltmeter. The sensor was capable of following a variety of different respiration patterns during normal breathing, exercise and rest, at the same time powered only by electromagnetic energy harvested from the human body. Everything happened in the normal environment used for everyday work and life, without any additional sources, and at a safe level of electromagnetic radiation.

M. Ognjanović, K. Nikolić, M. Bošković, F. Pastor, N. Popov, M. Marciuš, S. Krehula, B. Antić, D. Stanković

Morphine (MORPH) is natural alkaloid and mainly used as a pain reliever. Its monitoring in human body fluids is crucial for modern medicine. In this paper, we have developed an electrochemical sensor for submicromolar detection of MORPH. The sensor is based on modified carbon paste electrode (CPE) by investigating the FexW1-xO4 ratio in iron tungstate (FeWO4), as well as the ratio of this material in CPE. For the first time, the effect of the iron–tungsten ratio in terms of achieving the best possible electrochemical characteristics for the detection of an important molecule for humans was examined. Morphological and electrochemical characteristics of materials were studied. The best results were obtained using Fe1W3 and 7.5% of modifier in CPE. For MORPH detection, square wave voltammetry (SWV) was optimized. Under the optimized conditions, Fe1W3@CPE resulted in limit of detection (LOD) of the method of 0.58 µM and limit of quantification (LOQ) of 1.94 µM. The linear operating range between 5 and 85 µM of MORPH in the Britton–Robinson buffer solution (BRBS) at pH 8 as supporting electrolyte was obtained. The Fe1W3@CPE sensor resulted in good selectivity and excellent repeatability with relative standard deviation (RSD) and was applied in real-world samples of human urine. Application for direct MORPH detection, without tedious sample pretreatment procedures, suggests that developed electrochemical sensor has appeared to be a suitable competitor for efficient, precise, and accurate monitoring of the MORPH in biological fluids.

Kristina Radinović, J. Milikić, A. Balčiūnaitė, Z. Sukackienė, M. Bošković, L. Tamašauskaitė-Tamašiūnaitė, B. Šljukić

Six cobalt gold (CoAu) electrodes were prepared by electroless deposition using different gold-containing solutions (acidic and weakly acidic) and different Au deposition times. Characterization of CoAu electrodes was done by scanning electron microscopy with energy-dispersive X-ray spectroscopy, N2-sorption, and X-ray powder diffraction techniques. The possibility of using the prepared electrodes in environmental applications, i.e., for the electrochemical sensing of a trace amount of arsenic(iii) in weakly alkaline media was assessed. Employing the CoAu electrode (prepared by immersing Co/Cu into 1 mM HAuCl4 (pH 1.8) at 30 °C for 30 s) under optimized conditions (deposition potential −0.7 V and deposition time of 60 s), a low limit of detection of 2.16 ppb was obtained. Finally, this CoAu electrode showed activity for arsenic oxidation in the presence of Cu(ii) as a model interferent as well as in real samples. Furthermore, the use of CoAu electrode as an anode in fuel cells, namely, direct borohydride – hydrogen peroxide fuel cells was also assessed. A peak power density of 191 mW cm−2 was attained at 25 °C for DBHPFC with CoAu anode at a current density of 201 mA cm−2 and cell voltage of 0.95 V, respectively. The peak power density further increased with the increase of the operating temperature to 55 °C.

M. Bošković, Stanislav Andreev, D. Schollmeyer, P. Koch

Reaction of diphenylmethanol (4) with n-butyllithium and subsequent treatment with selenium resulted in 12H-dibenzo[d,g][1,2,3]triselenocin-12-ol (5) comprising a novel heterocyclic ring system. The title compound 5 was analyzed by 1H-NMR, 13C-NMR and HPLC. Additionally, the structure of 5 was confirmed by single crystal X-ray diffraction.

I. Mladenović, M. Bošković, M. Vuksanović, N. Nikolić, J. Lamovec, D. Vasiljević-Radović, V. Radojević

Mechanical (hardness and adhesion) and electrical (sheet resistance) characteristics of electrolytically produced copper coatings have been investigated. Morphologies of Cu coatings produced galvanostatically at two current densities from the basic sulfate electrolyte and from an electrolyte containing levelling/brightening additives without and with application of ultrasound for the electrolyte stirring were characterized by SEM and AFM techniques. Mechanical characteristics were examined by Vickers microindentation using the Chen–Gao (C–G) composite hardness model, while electrical characteristics were examined by the four-point probe method. Application of ultrasound achieved benefits on both hardness and adhesion of the Cu coatings, thereby the use of both the larger current density and additive-free electrolyte improved these mechanical characteristics. The hardness of Cu coatings calculated according to the C–G model was in the 1.1844–1.2303 GPa range for fine-grained Cu coatings obtained from the sulfate electrolyte and in the 0.8572–1.1507 GPa range for smooth Cu coatings obtained from the electrolyte with additives. Analysis of the electrical characteristics of Cu coatings after an aging period of 4 years showed differences in the sheet resistance between the top and the bottom sides of the coating, which is attributed to the formation of a thin oxide layer on the coating surface area.

N. Popov, M. Bošković, M. Perović, K. Zadro, V. Gilja, L. K. Krehula, Marko Robić, M. Marciuš, M. Ristić et al.

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