Urbanisation and land-use change are among the main pressures on soil health in periurban areas, but the multifunctionality of grassland soils is still not sufficiently recognised. In this study, the physical and chemical properties of soils under grassland, forest and croplands in the periurban area of Zagreb were investigated in a two-year period. Grasslands consistently exhibited multifunctional benefits, including high organic matter content (4.68% vs. 2.24% in cropland), improved bulk density (1.14 vs. 1.24 g cm−3) and an active carbon cycle indicated by increased CO2 emissions (up to 1403 kg ha−1 day−1 in 2021). Forest soils showed the highest aggregate stability (91.4%) and infiltration (0.0006 cm s−1), while croplands showed signs of structural degradation with the highest bulk density and lowest water retention (39.9%). Temporal variation showed that grassland was particularly responsive to favourable climatic conditions, with soil porosity and water content improving yearly. Principal component analysis showed that soil structure, biological activity and moisture regulation were linked, with grassland plots favourably positioned along the axes of resilience. The absence of tillage and the presence of permanent vegetation cover contributed to their high capacity for climate and water regulation and carbon sequestration. These results emphasise the importance of protecting and managing grasslands as an important component of urban green areas. Practices such as mulching, minimal disturbance and continuous cover can maximise the ecosystem services of grassland soils. In addition, the results highlight the potential risk of trace metal accumulation in cropland and grassland soils located near urban and farming infrastructure, underlining the need for regular monitoring in periurban environments. Integrating grassland functions into urban planning and policy is essential for improving the sustainability and resilience of periurban landscapes.

A future radioactive waste management centre is under development in central Croatia. One of the activities in the centre’s development was to monitor environmental radioactivity before the disposal of radioactive materials. Part of the monitoring programme focused on soil characterisation in the municipality (total area 1308 km2) surrounding the centre, where about 40% of the soil is today used in organic farming. The study included a physico-chemical and radionuclide characterisation of the soil as well as ambient dose rate measurements. The aim of this study was to investigate how the physical and chemical composition of soil affects the concentration of radionuclides 238U, 40K, and 137Cs in soil, based on the measured radionuclide concentrations and values of selected soil parameters. Additionally, the ambient equivalent dose rate H*(10)/t was measured and the annual effective dose was calculated for the average person living in the area of interest. The observed ranges of radionuclide concentrations in the soil samples were: 9–72 Bq/kg for 238U, 65–823 Bq/kg for 40K, and 4–80 Bq/kg for 137Cs. Ambient dose equivalent rate measurements were in the range of 52–130 nSv/h. The highest measured values were in correlation with higher 238U activity concentrations in these parts of the investigated area. The results of this study showed that 238U had a significant correlation with pH; plant available P; sand, silt, and clay content; hydrolytic acidity; CaCO3; total carbon, organic matter, and total inorganic and organic carbon; and concentrations of Al, Si, Fe, Ca, Ti, K, Rb, Zr, Nb, Y, Sr, Th, and W. 40K showed a significant correlation with pH, sand content, hydrolytic acidity, total hydrogen, total nitrogen, CaCO3, total carbon, total inorganic carbon, and concentrations of Al, Si, Fe, Ca, Ti, Rb, Zr, Nb, P, Y, Zn, and Th. 137Cs showed a significant correlation with silt content, total nitrogen, and Si concentration.

In this study, the effect of ammunition on soil quality (physical and chemical indicators) at shooting ranges was investigated at four sites in Croatia. The sites differ in soil type (fluvisols, leptosols and terra rossa) and climatic conditions (Mediterranean and continental). The intensity of shooting range use (calculated from the age of the lane and the average number of targets used per year) and the distance from the shooting range (−40 m to +240 m) were examined in relation to soil chemical composition and soil quality. High contents of Pb and Sb at 100 m from the shooting position were observed in fluvisol and terra rossa soils, and the contamination factors (CFs) ranged from 6 up to 97. The study found high natural soil Cr and Ni content in leptosols and terra rossa due to paedogenic reasons (CFs < 1.3) and soil acidification (a decrease in soil pHKCl) due to ammunition/target use. Long-term measures for sustainable soil management and environment protection must be taken at shooting ranges to minimise the potential risks to ecosystems, wildlife and human health (an EU strategy).

Selecting cultivars with greater biomass results in higher yields and greater carbon sequestration. Storage of atmospheric carbon in the plant/soil pool contributes not only to food security but also to mitigating climate change and other agroecological benefits. The objective of this study was to determine: (1) grain, residue, and root biomass yields; (2) harvest indexes; (3) residue-to-product ratio; (4) root-to-shoot ratio; (5) biomass carbon and nitrogen contents; and (6) C:N ratios for two new and two old winter wheat cultivars. The greatest yield difference was found between old Srpanjka (the lowest) and new Kraljica (the highest) cultivar where grain, residue, root, and total biomass yield was higher by 38%, 91%, 71%, and 64%, respectively. Total biomass was composed of 40–47% grain, 10–11% roots, 32–36% stems + leaves, 9–11% chaff, and 1–2% spindle. The range of HI was 0.45–0.53, RPR 0.91–1.25, and R:S ratio 0.12–0.13. For all cultivars, positive carbon and negative nitrogen balance within the plant pool was determined. Still, root biomass and rhizodeposition carbon remain open questions for a better understanding of agroecosystems’ C dynamics.

Sustainable management of agricultural resources is needed to meet people’s increasing demands for food, fiber and energy while maintaining the quality of the environment and protecting natural resources. With the rapid growth of agriculture and the mechanization of farming, the agricultural sector has become one of the main contributors to the increase in CO2 emissions and other greenhouse gases in the world. Therefore, the aim of this study was to determine the effect, dependence and correlations of CO2 in soil with native vegetation (presence/absence, corn yield) and climatic conditions (soil temperature and moisture) during three years of measurements under different management practices in a classical conventional agroecosystem. This research contains four different treatments: control treatment (CT), dolomite/organic fertilization (DOL/OF), mineral fertilization (MF) and black fallow (BF). During the investigated period, the average overall C-CO2 flux ranged from 7.98 kg ha−1 day−1 on bare soil to 16.26 kg ha−1 day−1 on soil treated with mineral fertilization. No statistically significant difference was observed among different fertilization treatments, except in 2013 and 2015 when comparing different fertilization treatments to bare soil. In all three years, there was a positive correlation between average C-CO2 fluxes and soil temperature. Additionally, in 2013 and 2017, there was a positive correlation between average C-CO2 fluxes and soil moisture, while a negative correlation was observed in 2015. Obtained values of crop yield ranged from 0.89 t ha−1 in the control treatment (in 2015) to 14.81 t ha−1 in the treatment with mineral fertilization (in 2017). Growing global concern about the effects of climate change calls for intensive research on the carbon cycle, and these results will contribute to the understanding of carbon transformation in different crops and soil management practices.

The purpose of this paper is to explore whether or not fiscal policy can stimulate the economic activity in the Federation of Bosnia and Herzegovina. For this purpose, the time-series data are collected in the period 2008-2014. The results suggest that a unit increase in revenue leads to a reduction in the gross domestic product in the long-run. Budgetary expenditures are found to stimulate gross domestic product only in initial period. However, results in the long-run are found to be negligible. Moreover, impulse-response function indicates there are many other determinants of gross domestic product in the Federation of Bosnia and Herzegovina besides budgetary expenditures. Therefore, the impact of fiscal policy on economic growth is just partial. Hence, development policy based on budgetary expenditures will lead to only small increase in economic output.

Biological carbon sequestration is considered an important strategy to mitigate climate change. The energy crop Miscanthus × giganteus has great sequestration potential. The objective of this study was to determine: a) the dry matter yield and carbon content in aboveground and belowground biomass; b) the total carbon balance in the plant and soil pool. The study was conducted in continental Croatia (N 45°51′01.32″; E 16°10′35.85″) by the destructive harvesting of five-year-old Miscanthus × giganteus stands established by rhizomes (MxgR) and seedlings (MxgS) in the spring of 2021. The soil sampling was conducted in 2016 and 2022. The average amount of carbon in the aboveground biomass of MxgR and MxgS is 11.51 t/ha and 9.87 t/ha, respectively, and in the belowground biomass it is 13.18 t/ha and 14.90 t/ha, respectively. The carbon balance in the plant pool of MxgR is three times lower (1.67 t/ha) than that in the plant pool of MxgS (5.03 t/ha). The total soil carbon content increased by 8.7 t/ha under MxgR and by 14.8 t/ha under MxgS during 2016–2022. Therefore, under the studied agroecological conditions, seedlings should be preferred over rhizomes in the selection of planting material. The obtained data represent valuable input data for sequestration modeling.

Soil respiration is a significant contributor to the global emissions of CO2 and is governed by many soil factors. Reliable estimates of CO2 emission on different scales (e.g., field, regional level) are hard to obtain due to the expressed spatial and temporal variability of the CO2 flux. This study aims to investigate the spatial variability of CO2 flux and soil properties in soybean cropland on Fluvisols (Croatia). The field measurements and soil samples were taken in a regular sampling grid (2 × 2 m) with 44 points in total and the spatial variability was assessed using the kriging and cokriging techniques. The soil CO2 flux showed relatively high spatial heterogeneity, ranging from 0.03 mg/m2s to 0.40 mg/m2s. The soil organic matter content (SOM), soil water content (SWC), and soil temperature (ST) had the lower variability ranging from 2.09% to 2.52%, from 27.7% to 46.8%, and from 13.7 °C to 18.2 °C, respectively. The spatial dependence was high for CO2 flux and ST, moderate for SOM, and low for SWC. The incorporation of the auxiliary variables increased the precision of the estimations for CO2 flux, SOM, and SWC. Kriging was the most accurate method for the spatial prediction of ST. The SWC was associated as the most important factor of the CO2 fluxes, indicated by their significant negative correlation, and the highest increase of the prediction precision during spatial modeling. However, more robust co-variates should be incorporated in future models to further increase the precision.

<p>In order to mitigate climate change and reduce the anthropogenic greenhouse gas (GHG) emissions, the Kyoto protocol has been adopted in 1997 and the Paris Agreement entered into force in 2016. The Paris Agreement have ratified 190 out of 197 Parties of the United Nations Framework Convention on Climate Change (UNFCCC) and Croatia is one of them as well. Each Party has obliged regularly to submit the national inventory report (NIR) providing the information on the national anthropogenic GHG emissions by sources and removals by sinks to the UNFCCC. Reporting under the NIR is divided into six categories / sectors, and one of them is land use, land use change and forestry (LULUCF) sector, where an issue of uncertainty estimates on carbon emissions and removals occurs. As soil respiration represents the second-largest terrestrial carbon flux, the national studies on soil respiration can reduce the uncertainty and improve the estimation of country-level carbon fluxes. Due to the omission of national data, the members of the University of Zagreb Faculty of Agriculture, Department of General Agronomy have started to study soil respiration rates in 2012, and since then many different studies on soil respiration under different agricultural land uses (i.e. annual crops, energy crop and vineyard), management practices (i.e. tillage and fertilization) and climate conditions (i.e. continental and mediterranean) in Croatia have been conducted. The obtained site specific results on field measurements of soil carbon dioxide concentrations by <em>in situ</em> closed static chamber method will be presented in this paper.</p>

Nitrogen oxides play a major role in atmospheric chemistry, like primary pollutants, in the formation of secondary air pollutants or greenhouse gases (GHGs). This research study was conducted in the Western Pannonian sub-region of Croatia with the aim to determine the suitability of our internally developed passive sampler and static chamber method for N-NO2 concentration measurement. The aim was also to determine the impact of mineral soil fertilization on the N-NO2 flux during triticale vegetation. The research showed that the method used was suitable. Average daily N-NO2 flux ranged from 2.78 to 5.09 mg ha−1 day−1 depending on phenophase and treatment. Statistically significant differences in N-NO2 flux between two monitored treatments (300 kg N ha−1 and 0 kg N ha−1) were not observed, nor between two investigated phenophases.